焓,表征系统中所有的总能量,它是内能与压力位能之和.

对1公斤工质而言,用符号i表示

单位是kcal/kg.

即i=u+APv

kcai/kg。

式中u---内能

kcai/kg.

...P---压力

kgf/㎡.

...v---比容

m³/kg.

...A---功的热当量

A=(1/426.9)kcal/kg*m.

或者以G公斤工质的焓用I表示:I=Gi.

通过工质的热力性质表可查到该工质在某温度(T)时所对应的压力、比容、比重和两态焓值。

蒸汽焓值计算

焓值计算:H=2022.7+1.6675×T+2.9593×10^(-4)×T^2-1.2690×10^9×P/T^2.7984-1.0185×10^23×P^2/T^8.3077

P-MPa,T-KH-kJ/kg

一阶拟合:

Linear model Poly1:

f(x) = p1*x + p2

Coefficients (with 95% confidence bounds):

p1 = 1.569 (1.528, 1.61)

p2 = 2507 (2504, 2511)

Goodness of fit:

SSE: 3469

R-square: 0.9916

Adjusted R-square: 0.9914

RMSE: 8.414

Linear model Poly1:

f(x) = p1*x + p2

Coefficients (with 95% confidence bounds):

p1 = 1.67 (1.659, 1.682)

p2 = 2504 (2503, 2504)

Goodness of fit:

SSE: 252.6

R-square: 0.9994

Adjusted R-square: 0.9994

RMSE: 2.271

Linear model Poly1:

f(x) = p1*x + p2

Coefficients (with 95% confidence bounds):

p1 = 1.777 (1.765, 1.789)

p2 = 2502 (2501, 2503)

Goodness of fit:

SSE: 295.6

R-square: 0.9993

Adjusted R-square: 0.9993

RMSE: 2.456

二阶拟合:

Linear model Poly2:

f(x) = p1*x^2 + p2*x + p3

Coefficients (with 95% confidence bounds):

p1 = -0.002719 (-0.002911, -0.002526)

p2 = 2.036 (2.002, 2.071)

p3 = 2499 (2498, 2500)

Goodness of fit:

SSE: 195.7

R-square: 0.9995

Adjusted R-square: 0.9995

RMSE: 

蒸汽焓值计算

焓值计算:H=2022.7+1.6675×T+2.9593×10^(-4)×T^2-1.2690×10^9×P/T^2.7984-1.0185×10^23×P^2/T^8.3077

P-MPa,T-KH-kJ/kg